Photo from academic.microsoft.com
Abstract Ternary complexes of Cr(III) with l -histidine monohydrochloride and various diols of the type MAB, MA 2 B and MAB 2 were synthesized and characterized in the present study.… Click to show full abstract
Abstract Ternary complexes of Cr(III) with l -histidine monohydrochloride and various diols of the type MAB, MA 2 B and MAB 2 were synthesized and characterized in the present study. The structural properties of complexes were derived from the elemental analysis and magnetic characterization. The elemental analysis and magnetic characterization indicated that they have the octahedral stereochemistry with three unpaired electrons. The values of Dq/B were of greater magnitude for MA 2 B type species as compared to MAB and MAB 2 species. Values of nephelauxetic ratio β 55 (for spin forbidden band) were found to be more than β 35 (for spin allowed transition).
Journal Title: Arabian Journal of Chemistry
Year Published: 2017
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!