LAUSR

Abstract Hydrogen sulfide has been successfully removed from biogas using anoxic biotrickling filters but an in-depth study of the main operational variables has not yet been carried out. The effect of (i) the empty bed residence time (32–164 s) at a hydrogen sulfide concentration of 2,000 ppmv, (ii) the inlet hydrogen sulfide concentration (2,000–10,000 ppmv), (iii) the trickling liquid velocity (4.8–20.9 m h−1) and (iv) the feed of low nitrogen/sulfur molar ratio (0.334–0.409 mol N-NO3– mol−1 S-H2S) on the hydrogen sulfide removal efficiency have been studied. The BTF (total packed volume of 2.8 L, height/diameter ratio of 9.8) was filled with polypropylene Pall rings (5/8″) and fed continuously with nitrate and a biogas mimic operating in counter-current and co-current flow modes. The maximum elimination capacity was 282.0 gS-H2S m–3  h–1 (RE 97 ± 0.5%) for counter-current flow and 287.5 gS-H2S m–3 h–1 (RE 99 ± 0.4%) for co-current flow mode for an EBRT of 164 s. In addition, in terms of the nitrogen/sulfur molar ratio a higher elemental sulfur production was found in counter-current flow (97.6 ± 2.0%) when compared to co-current flow (87.6±2.8%) since a better depletion of nitrate occurred in co-current flow mode. Finally, three different nitrogen/sulfur molar ratios (0.4, 1.0 and 1.6 mol N-NO3– mol–1 S-H2S) were compared economically. The low and high ratios would involve a nitrate cost of 0.54 and 2.15 € per kg of treated of S-H2S and an elemental sulfur production of 21.5 metric tons and zero production, respectively.