LAUSR

Pollutants containing sulfur as electron donors will play an important role in the energy-saving denitritation process when organic carbon source was insufficient in wastewater. However, thiocyanate (SCN-), a hazardous pollutant, has not been characterized in denitritation. In this study, the effects of key environmental factors on removal of thiocyanate and nitrogen were investigated in denitritation. The results showed that the maximum removal efficiency of nitrogen was observed in complete removal of thiocyanate and nitrite. The elemental sulfur was observed prior to complete depletion of thiocyanate. The efficiency of denitritation was promoted by NaHCO3 and weakly-alkaline environment. In the sludge containing dominant Thiobacillus genus, nitrite was reduced in the conversion of thiocyanate into elemental sulfur and further into sulfate. The stoichiometric ratio of NO2--N to SCN--N was close to 2.0 when thiocyanate was converted completely into sulfate, which verified complete removal of thiocyanate and nitrite at the NO2--N/SCN--N ratio of 2.0.