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Effect of phase type in the alumina precursor on the flash calcination synthesis

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Abstract Economical alumina precursors, derived from bauxite or nepheline ores, were calcined through a very short time process. Results showed that phases of the precursor are a key parameter on… Click to show full abstract

Abstract Economical alumina precursors, derived from bauxite or nepheline ores, were calcined through a very short time process. Results showed that phases of the precursor are a key parameter on the flash calcination process. The number of structural water molecules is the dominant phenomenon. A porous and fine structure of activated alumina was developed as the hydroxyl groups are explosively driven off and establish a hydrothermal condition. The presence of gibbsite phase with larger particle size and most structural water molecules has better product properties in comparison of other alumina precursors phase with small particle size because water vapor pressure achieves a critical value for splitting particles and developing nucleation desirable phases. The changes rate of properties reaches to its maximum value for gibbsite phase at lower calcination temperature. FESEM images showed the precursor phase forms different morphologies of products like, nanodimensional, a coral-like co-continuous or loose particles surrounded with macropores.

Keywords: flash calcination; phase type; calcination; alumina; effect phase; phase

Journal Title: Boletin De La Sociedad Espanola De Ceramica Y Vidrio
Year Published: 2021

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