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Probing basal planes and edge sites in polygranular nuclear graphite by gas adsorption: Estimation of active surface area

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Abstract Polygranular nuclear graphite, manufactured at 2800–3000 °C from a carbonized filler and binder mix, has high graphitization degree, crystalline structure close to perfect graphite, and about 20 % porosity.… Click to show full abstract

Abstract Polygranular nuclear graphite, manufactured at 2800–3000 °C from a carbonized filler and binder mix, has high graphitization degree, crystalline structure close to perfect graphite, and about 20 % porosity. The pore surfaces expose large regions of rough, defective prismatic edges of graphite crystallites which are the locus of graphite materials surface sites active for oxidation, chemisorption, and electron transfer. However, we show that high-resolution N2 and Kr first monolayer adsorption on polygranular graphite (P/P0

Keywords: basal planes; polygranular nuclear; nuclear graphite; adsorption; graphite; probing basal

Journal Title: Carbon
Year Published: 2021

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