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Functionalization of cellulosic fibers with a kaolinite-TiO2 nano-hybrid composite via a solvothermal process for flame retardant applications.

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Eco-responsible flame retardant treatments with some resistance to washing are of considerable interest in the sale and applications of technical garments and home textiles. Thus, in the present study, a… Click to show full abstract

Eco-responsible flame retardant treatments with some resistance to washing are of considerable interest in the sale and applications of technical garments and home textiles. Thus, in the present study, a nano-hybrid composite based on kaolinite-TiO2 was prepared and incorporated into the fibers of cotton fabric through a more sustainable route compared to existing commercial processes. SEM analyses revealed a mineral covering of the treated cotton fibers, which do not propagate flames when exposed to fire and have a self-extinguishing behavior after the heat source removal. The method proved to be efficient in obtaining a cotton product with high fireproof performance. It was observed that after functionalization, the fabric showed a thermal degradation 41% less at 800 °C, an increase in the residue formation, and a reduction of about 85% in peak heat release measured by PCFC. Some resistance to washing was noticed, and the mechanical resistance of fibers was preserved.

Keywords: kaolinite tio2; flame retardant; hybrid composite; nano hybrid

Journal Title: Carbohydrate polymers
Year Published: 2021

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