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Synthesis of the 6-deoxy-talose (6-dTal) containing tetrasaccharide, naturally found in Franconibacter helveticus LMG23732T, has been described. The synthetic method utilized an allyloxyethylidene group for protecting the 1-OH and 2-OH groups… Click to show full abstract
Synthesis of the 6-deoxy-talose (6-dTal) containing tetrasaccharide, naturally found in Franconibacter helveticus LMG23732T, has been described. The synthetic method utilized an allyloxyethylidene group for protecting the 1-OH and 2-OH groups of rhamnopyranose and a redox reaction for synthesizing 6-deoxy talose, which eventually formed a disaccharide containing α-Glcp-(1→2)-6dTalp configured glycosidic bonds using a [2 + 2] synthetic strategy.
Keywords:
synthesis deoxy;
found franconibacter;
helveticus lmg23732t;
franconibacter helveticus;
deoxy talose
Journal Title: Carbohydrate research
Year Published: 2018
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Journal Title: Carbohydrate research
Year Published: 2018
Link to full text (if available)
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recommendations!