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A highly efficient oxidative C2-aroyloxylation of D-glucal with aromatic carboxylic acids has been achieved for the first time using 5 mol% Pd(OAc)2 and 1 equiv of PhI(OAc)2 to produce C2-aroyloxyglycals in… Click to show full abstract
A highly efficient oxidative C2-aroyloxylation of D-glucal with aromatic carboxylic acids has been achieved for the first time using 5 mol% Pd(OAc)2 and 1 equiv of PhI(OAc)2 to produce C2-aroyloxyglycals in good yields. The use of excess of PhI(OAc)2 (2 equiv) provides C2-acyloxyglycal exclusively.
Keywords:
direct cross;
oac promoted;
phi oac;
promoted direct;
coupling glucals;
cross coupling
Journal Title: Carbohydrate research
Year Published: 2018
Link to full text (if available)
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Journal Title: Carbohydrate research
Year Published: 2018
Link to full text (if available)
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recommendations!