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Selective acetolysis of the primary benzyloxy groups in a wide variety of carbohydrate derivatives was achieved in excellent yield using acetic anhydride and perchloric acid supported over silica (HClO4-SiO2) as… Click to show full abstract
Selective acetolysis of the primary benzyloxy groups in a wide variety of carbohydrate derivatives was achieved in excellent yield using acetic anhydride and perchloric acid supported over silica (HClO4-SiO2) as a solid acid catalyst in a fast reaction condition without using any organic solvent. The reaction condition is significantly rapid and can be scaled up for its use in the multi-step oligosaccharide synthesis.
Keywords:
reaction condition;
selective acetolysis;
carbohydrate derivatives;
reaction;
acetolysis primary
Journal Title: Carbohydrate research
Year Published: 2019
Link to full text (if available)
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Journal Title: Carbohydrate research
Year Published: 2019
Link to full text (if available)
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recommendations!