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A visible light promoted O-glycosylation with glycosyl trichloroacetimidates using eosin Y as an organo photoacid.

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A photoacid catalyzed O-glycosylation of alcohols with glycosyl trichloroacetimidates in the presence of commercially available phenolic photoacids, fluorescein, 4',5'-dibromo-fluorescein, and eosin Y under visible light irradiation by blue LEDs was… Click to show full abstract

A photoacid catalyzed O-glycosylation of alcohols with glycosyl trichloroacetimidates in the presence of commercially available phenolic photoacids, fluorescein, 4',5'-dibromo-fluorescein, and eosin Y under visible light irradiation by blue LEDs was developed. The method is operationally simple without neutralization and proceeds at room temperature.

Keywords: glycosyl trichloroacetimidates; photoacid; visible light; promoted glycosylation; light promoted

Journal Title: Carbohydrate research
Year Published: 2020

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