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Oxygen vacancy induced enhancement of photochemical water oxidation on calcium manganese oxide catalyst

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Abstract The oxygen-deficient Ca 2 Mn 2 O 5 perovskite nanoparticles exhibit remarkably higher catalytic activity compared to CaMnO 3 and MnO 2 nanoparticles for photochemical water oxidation. The fraction… Click to show full abstract

Abstract The oxygen-deficient Ca 2 Mn 2 O 5 perovskite nanoparticles exhibit remarkably higher catalytic activity compared to CaMnO 3 and MnO 2 nanoparticles for photochemical water oxidation. The fraction of surface adsorbed hydroxyl groups on these catalysts has been suggested to be the dominant factors affecting water oxidation activity compared to the other parameters such as oxidation states of manganese and crystal structure.

Keywords: oxygen vacancy; water; photochemical water; water oxidation; vacancy induced

Journal Title: Catalysis Communications
Year Published: 2017

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