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Wet air oxidation of fracturing flowback fluids over promoted bimetallic Cu-Cr catalyst

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Abstract Fracturing flowback fluid (FFF) is one of the most toxic effluents in oil and gas fields. The catalysts prepared by excessive impregnation were used wet air oxidation (CWAO) of… Click to show full abstract

Abstract Fracturing flowback fluid (FFF) is one of the most toxic effluents in oil and gas fields. The catalysts prepared by excessive impregnation were used wet air oxidation (CWAO) of FFFs at oxygen partial pressure (PO 2 ) of 2.5 MPa and temperature of 250 °C. Catalysts were characterized by H 2 -TPR, XRD, SEM and EDS. Results revealed that the activated carbon (AC) supported Cu Cr had a better catalytic performance due to superior dispersion, lower reduction temperature, and strong interaction between Cu and Cr. Using the optimal 5%Cu1%Cr/AC catalyst (loading 10 g/L), about 97% chemical oxygen demand (COD) can be removed.

Keywords: fracturing flowback; wet air; catalyst; air oxidation

Journal Title: Catalysis Communications
Year Published: 2017

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