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iTPR - a new methodical approach for temperature programmed reduction of catalysts with improved sensitivity

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Abstract A new method for temperature programmed reduction (TPR) of reducible bulk or supported metal compounds with hydrogen is presented. The setup, involving a flame ionization detector (FID) and methanizer,… Click to show full abstract

Abstract A new method for temperature programmed reduction (TPR) of reducible bulk or supported metal compounds with hydrogen is presented. The setup, involving a flame ionization detector (FID) and methanizer, allows to study the reduction behavior of amounts down to 0.1 mg as shown for the reduction of Cu2O. By co-feeding CO2 in excess, hydrogen is converted into methane which is then detected by the FID.

Keywords: reduction; temperature programmed; new methodical; itpr new; programmed reduction

Journal Title: Catalysis Communications
Year Published: 2017

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