Abstract A new method for temperature programmed reduction (TPR) of reducible bulk or supported metal compounds with hydrogen is presented. The setup, involving a flame ionization detector (FID) and methanizer,… Click to show full abstract
Abstract A new method for temperature programmed reduction (TPR) of reducible bulk or supported metal compounds with hydrogen is presented. The setup, involving a flame ionization detector (FID) and methanizer, allows to study the reduction behavior of amounts down to 0.1 mg as shown for the reduction of Cu2O. By co-feeding CO2 in excess, hydrogen is converted into methane which is then detected by the FID.
               
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