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Cu doped amine functionalized graphene oxide and its scope as catalyst for selective oxidation

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Abstract We describe the synthesis of Cu doped amine functionalized graphene oxide (Cu@AGO) and its effective application as recyclable heterogeneous catalyst for selective partial oxidation of benzyl alcohols to corresponding… Click to show full abstract

Abstract We describe the synthesis of Cu doped amine functionalized graphene oxide (Cu@AGO) and its effective application as recyclable heterogeneous catalyst for selective partial oxidation of benzyl alcohols to corresponding benzaldehydes under mild conditions with acetonitrile as solvent. The Cu@AGO was fully characterized by XRD, FT-IR, Raman spectra, XPS, SEM and TEM analysis. FT-IR validated the successful grafting of organic amine with graphene oxide, while TEM confirmed the uniform distribution of metal particles on amine functionalized graphene oxide. The catalyst gave excellent conversion (92%) and selectivity (99%) towards benzaldehyde, with good reusability up to 4 cycles.

Keywords: graphene oxide; amine functionalized; functionalized graphene; catalyst selective; doped amine

Journal Title: Catalysis Communications
Year Published: 2017

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