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Further activation of g-C3N4 with less N-H defects for enhancing photocatalytic hydrogen evolution

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Abstract g-C3N4 was further treated with N2-assisted pyrolysis, during which some gaseous derivatives were released from the surface of g-C3N4 at 550 °C, producing novel carbon nitride (CNH) with the high… Click to show full abstract

Abstract g-C3N4 was further treated with N2-assisted pyrolysis, during which some gaseous derivatives were released from the surface of g-C3N4 at 550 °C, producing novel carbon nitride (CNH) with the high surface area and less N-H defects. As a result, CNH shows 14 times higher photocatalytic hydrogen evolution activity than the pristine g-C3N4. To some extent, this work provides deep understanding for the activation or reactivation of g-C3N4 in the catalysis.

Keywords: hydrogen evolution; c3n4; photocatalytic hydrogen; less defects

Journal Title: Catalysis Communications
Year Published: 2019

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