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Abstract A facile and efficient one-pot synthesis of methyl carbamate (MC) by urea and methanol was studied using metal modified fluorapatite as a catalyst. M5Ca5(PO4)6F2 (M5FAP, M = Co, Ni, Cu, Zn)… Click to show full abstract
Abstract A facile and efficient one-pot synthesis of methyl carbamate (MC) by urea and methanol was studied using metal modified fluorapatite as a catalyst. M5Ca5(PO4)6F2 (M5FAP, M = Co, Ni, Cu, Zn) was synthesized by co-precipitation. Among the catalysts, Zn5Ca5(PO4)6F2 (Zn5FAP) displayed the higher activity, selectivity and excellent stability after five times of reuse. A possible synthesis reaction mechanism over Zn5FAP catalyst was discussed.
Keywords:
synthesis methyl;
methyl carbamate;
synthesis;
m5ca5 po4;
po4 6f2;
one pot
Journal Title: Catalysis Communications
Year Published: 2019
Link to full text (if available)
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Journal Title: Catalysis Communications
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!