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Abstract Based on the acid-base mixed-ligand assembly strategy, a stable Mn(II)-based metal-organic framework (denoted as Mn-MOFs), containing 1-D Mn–O–C rod-shaped chains, was hydrothermally synthesized and structurally characterized. This material was… Click to show full abstract
Abstract Based on the acid-base mixed-ligand assembly strategy, a stable Mn(II)-based metal-organic framework (denoted as Mn-MOFs), containing 1-D Mn–O–C rod-shaped chains, was hydrothermally synthesized and structurally characterized. This material was demonstrated to be an efficient heterogeneous catalyst for the decarboxylative sulfonylation of cinnamic acids with sodium benzene sulfinates. Moreover, the Mn-MOF catalyst could be recycled up to six times with the retention of both catalytic activity and crystal structure.
Journal Title: Catalysis Communications
Year Published: 2019
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