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Cp*Rh(III)-catalyzed C(sp3) H alkenylation and arylation of 8-methylquinolines with quinones and thiophenes

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Abstract Rh(III)-catalyzed oxidative cross-coupling of C(sp3) H bonds with C(sp2) H bonds has been accomplished under mild conditions. This method furnishes a streamlined route for the C(sp3) H alkenylation and… Click to show full abstract

Abstract Rh(III)-catalyzed oxidative cross-coupling of C(sp3) H bonds with C(sp2) H bonds has been accomplished under mild conditions. This method furnishes a streamlined route for the C(sp3) H alkenylation and arylation of 8-methylquinolines. This protocol enables 8-methylquinolines to couple with different quinone and thiophene derivatives.

Keywords: sp3 alkenylation; iii catalyzed; alkenylation arylation; arylation methylquinolines

Journal Title: Catalysis Communications
Year Published: 2019

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