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Pressure-induced polymerization of butyndioic acid and its Li+ salt

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Abstract Conductive organic polymers with carbonyl groups are considered as potential cathode materials of the Li + battery. Driven by extremely high pressure, 2-butyndioic acid and its Li + salt… Click to show full abstract

Abstract Conductive organic polymers with carbonyl groups are considered as potential cathode materials of the Li + battery. Driven by extremely high pressure, 2-butyndioic acid and its Li + salt polymerize at around 4 and 10 GPa respectively, which demonstrates that pressure-induced polymerization is a robust method for synthesizing substituted polyacetylene-like conductors.

Keywords: pressure; acid salt; pressure induced; butyndioic acid; induced polymerization

Journal Title: Chinese Chemical Letters
Year Published: 2017

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