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Carbon dioxide-controlled assembly based on conjugated polymer and boron nitride

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Abstract CO2-controlled assembly of conjugated polymer and boron nitride (BN) was fabricated via electrostatic and hydrophobic interactions between the BN fiber and conjugated polymer of PFBT containing fluorene units and… Click to show full abstract

Abstract CO2-controlled assembly of conjugated polymer and boron nitride (BN) was fabricated via electrostatic and hydrophobic interactions between the BN fiber and conjugated polymer of PFBT containing fluorene units and 2,1,3-benzothiadiazole units. CO2, an effective and green stimulus for regulating the assembly of PFBT and BN fibers, leads to an obvious fluorescence variation. Moreover, PFBT enables the assembly with the signal amplification and light-harvesting properties. This work provides a new triggering method to construct intelligent conjugated polymer-based platform, and offers fluorescence monitoring strategy for carbon dioxide capture.

Keywords: polymer boron; boron nitride; controlled assembly; conjugated polymer; carbon dioxide

Journal Title: Chinese Chemical Letters
Year Published: 2020

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