Photo by sharonmccutcheon from unsplash
Abstract A four-step synthesis of methyl 6-formyl-2-hydroxy-4-methoxy-3-(3-methylbut-2-en-1-yl)benzoate (11) that can be used as building block for a facile synthesis of cajaninstilbene acid and its derivatives is reported. The synthesis of… Click to show full abstract
Abstract A four-step synthesis of methyl 6-formyl-2-hydroxy-4-methoxy-3-(3-methylbut-2-en-1-yl)benzoate (11) that can be used as building block for a facile synthesis of cajaninstilbene acid and its derivatives is reported. The synthesis of cajaninstilbene acid was accomplished in six steps with an overall yield of 20% starting from commercial materials by a synthesis whose key steps are TiCl4-mediated [3 + 3] cyclization and McMurry coupling.
Keywords:
synthesis cajaninstilbene;
cajaninstilbene acid;
acid derivatives;
facile synthesis
Journal Title: Chinese Chemical Letters
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Chinese Chemical Letters
Year Published: 2019
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!