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Formation of multiporous MnO/N-doped carbon configuration via carbonthermal reduction for superior electrochemical properties

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Abstract Herein, the multiporous MnO/N-doped carbon (MnO/NC) composite based on the abundant and inexpensive electrolytic manganese dioxide were fabricated through a facile microwave-assisted carbonthermal reduction, combined with a subsequent in-situ… Click to show full abstract

Abstract Herein, the multiporous MnO/N-doped carbon (MnO/NC) composite based on the abundant and inexpensive electrolytic manganese dioxide were fabricated through a facile microwave-assisted carbonthermal reduction, combined with a subsequent in-situ polymerization of polydopamine onto MnO along with thermal treatment. As an anode material, it retains a reversible capacity of 770.5 mAh g −1 at 300 mA g −1 and high Coulombic efficiency of 99% over 500 cycles, superior than those values of the pure multiporous MnO alone. The impressive performance is attributed to the splendid structure stability contributed by well-connected three-dimensional porous configuration and the enhanced reaction kinetics as well as electrical conductivity incurred by N-doped carbon layer with multiple type nitrogen.

Keywords: doped carbon; mno doped; carbonthermal reduction; mno; multiporous mno

Journal Title: Chemical Engineering Journal
Year Published: 2018

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