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Multiple polarization effect of shell evolution on hierarchical hollow C@MnO2 composites and their wideband electromagnetic wave absorption properties

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Abstract Nanoengineering technology has made great achievements, through the design of useful nanostructures and components, to provide us with more functional materials. Therefore, the ideal performance can be achieved by… Click to show full abstract

Abstract Nanoengineering technology has made great achievements, through the design of useful nanostructures and components, to provide us with more functional materials. Therefore, the ideal performance can be achieved by maximizing the contribution of nanostructures and components. As a typical material, core-shell material has been widely studied in order to find more possibilities in the nanoengineering applications. In this work, a designable core-shell composite material with graphitized tunable hollow carbon sphere as the core and sheet-like MnO2 particles as the shell is developed. The size and shell thickness of the core-shell shaped C@MnO2 was nearly 230, 40 nm, respectively. The correlation among shell-evolution, graphitized-tuned carbon core and their corresponding dielectric response ability has been well analyzed. The hollow carbon nanosphere@MnO2 with desirable real and imaginary permittivity (e'/e'') can be obtained in order to achieve the optimized electromagnetic (EM) absorption performance. One optimal reflection loss of −53.5 dB is gained at the thickness of 1.5 mm and the corresponding frequency region with RL

Keywords: absorption; shell; mno2; shell evolution; core

Journal Title: Chemical Engineering Journal
Year Published: 2020

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