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Microstructure and phase composition of CaO doped zirconia nanofibers

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Abstract CaO doped nanofibrous zirconia (ZrO 2 ) was fabricated by calcination of electrospun zirconium oxychloride (ZrOCl 2 )/ calcium nitrate (Ca(NO 3 ) 2 )/polyethylene oxide (PEO) composite fibers.… Click to show full abstract

Abstract CaO doped nanofibrous zirconia (ZrO 2 ) was fabricated by calcination of electrospun zirconium oxychloride (ZrOCl 2 )/ calcium nitrate (Ca(NO 3 ) 2 )/polyethylene oxide (PEO) composite fibers. ZrO 2 nanofibers were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray diffractometry (XRD). It is revealed that CaO content variation in ceramic filaments calcined at 1200 °C allows fabricating fully monoclinic, or fully cubic zirconia nanofibers, or nanofibers containing both tetragonal and cubic phases. CaO stabilized fully tetragonal zirconia nanofibers can be prepared at lower calcination temperature.

Keywords: zirconia nanofibers; cao doped; phase composition; microstructure phase; zirconia

Journal Title: Ceramics International
Year Published: 2017

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