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Enhancement of bonding network for silica sol bonded SiC castables by reactive micropowder

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Abstract Silica sol bonded castables have obvious advantages over low cement or hydratable alumina bonded castables in drying performance and sintering properties for SiC castables. However, they are not widely… Click to show full abstract

Abstract Silica sol bonded castables have obvious advantages over low cement or hydratable alumina bonded castables in drying performance and sintering properties for SiC castables. However, they are not widely used due to their weak strength at low temperature. The efficiency of bonding network for silica sol bonded SiC castable in the presence of different reactive micropowder such as SiO 2 micropowder and α-Al 2 O 3 micropowder was evaluated through oscillatory tests, sintered properties and microstructural analysis. Results show that the polymerization reaction between SiO 2 micropowders enhanced the siloxane network and reinforced the bonding strength, furthermore, the addition of α-Al 2 O 3 micropowder contributed to accelerating the formation of the siloxane network and hardening of the silica sol at lower temperatures and shorter time. Silica sol performed well as a binder agent for SiC castables with an addition content of 3 wt% SiO 2 micropowder and 2 wt% α-Al 2 O 3 micropowder, which showed high strength and good workability at room temperature. And Silica sol bonded SiC castable with the above micropowder contents possessed the best mechanical behavior after heat treatment due to combined binding of SiC whiskers and mullite.

Keywords: sol bonded; micropowder; network; silica sol

Journal Title: Ceramics International
Year Published: 2017

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