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Enhanced energy storage performance of Ba0.4Sr0.6TiO3 ceramics: Influence of sintering atmosphere

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Abstract Ba 0.4 Sr 0.6 TiO 3 (BST) powders were prepared by hydrothermal method, the ceramics were sintered in N 2 , air and O 2 atmosphere respectively. The effect… Click to show full abstract

Abstract Ba 0.4 Sr 0.6 TiO 3 (BST) powders were prepared by hydrothermal method, the ceramics were sintered in N 2 , air and O 2 atmosphere respectively. The effect of sintering atmosphere on the microstructure, dielectric properties, and energy storage performance of BST ceramics were investigated. The grain size of the BST ceramics sintered in O 2 atmosphere was reduced to 0.44 µm, indicating the grain growth was significantly inhibited with increasing oxygen partial pressure due to the lack of oxygen vacancy. Dielectric relaxation behavior was observed in the BST ceramics, and the degree of which was increased with increasing oxygen partial pressure. BST ceramics sintered in O 2 atmosphere showed the largest critical breakdown strength of 16.72 kV/mm, at which the highest energy storage density of 1.081 J/cm 3 and a moderate energy storage efficiency of (73.78%) were obtained. The dependence of energy-storage properties on applied field was also investigated, it was found that the energy storage density increased with increasing applied filed while the energy storage efficiency decreased with increasing applied filed.

Keywords: energy; bst ceramics; energy storage; sintering atmosphere; storage performance

Journal Title: Ceramics International
Year Published: 2017

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