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Comparative study on doping effects in Bi1−xDyxFe1−yMnyO3 nanoparticles fabricated by sol-gel technique

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Abstract We have studied the optical, electrical and magnetic properties of Dy and Mn doped BiFeO3 nanoparticle synthesized by the sol-gel technique. In the doped samples, a transition of crystal… Click to show full abstract

Abstract We have studied the optical, electrical and magnetic properties of Dy and Mn doped BiFeO3 nanoparticle synthesized by the sol-gel technique. In the doped samples, a transition of crystal structure was demonstrated by XRD. With increasing x from 0.00 to 0.10 and y from 0.00 to 0.05, the optical band gap of Bi1−xDyxFe1−yMnyO3 nanoparticles decreases and can be interpreted by the decreased particle size and the increased internal stress of samples, which caused by Dy, Mn doping. According to the data from X-ray photoelectron spectroscopy, the doping of Dy3+ and Mn2+ can availably restrain the transform from Fe3+ to Fe2+. A small leakage current density and large value of saturation magnetization are observed for the co-doped samples. Therefore, the doping of (Dy, Mn) is an effective mean to strengthen the multiferroic behavior of the nanoparticles.

Keywords: ymnyo3 nanoparticles; gel technique; bi1 xdyxfe1; xdyxfe1 ymnyo3; sol gel

Journal Title: Ceramics International
Year Published: 2017

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