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An efficient Sm and Ge co-doped ceria nanocomposite electrolyte for low temperature solid oxide fuel cells

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Abstract In this study we present a new nanocomposite electrolyte based on samarium (Sm) and germanium (Ge) co-doped ceria Ce 0.7 Sm 0.15 Ge 0.15 O 2-δ (SGeDC). The nanocomposite… Click to show full abstract

Abstract In this study we present a new nanocomposite electrolyte based on samarium (Sm) and germanium (Ge) co-doped ceria Ce 0.7 Sm 0.15 Ge 0.15 O 2-δ (SGeDC). The nanocomposite electrolyte was prepared using co-precipitation method. The crystal structure and surface morphology were determined using x-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Four probe dc conductivity indicated the value of 0.074 S/cm at 650 °C. The Fuel cell performance was carried out using hydrogen as fuel. The maximum OCV observed was 0.95 V while the peak power density came out to be 600 mW/cm 2 at 600 °C. It is suggested that adding Ge, the conductivity as well as performance of this new nanocomposite electrolyte is comparatively enhanced and it can find potential applications in low temperature solid oxide Fuel cells (LTSOFCs).

Keywords: nanocomposite electrolyte; low temperature; doped ceria; fuel; solid oxide; temperature solid

Journal Title: Ceramics International
Year Published: 2018

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