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Fabrication of efficient electrode material: CoxZn1-xFe2O4-graphene nano-heterostructures for high-performance supercapacitors

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Abstract Co0.3Zn0.7Fe2O4 nanoparticles prepared by co-precipitation method were characterized by X-ray diffraction (XRD). Reduced graphene oxide (rGO) was prepared by modified Hummer's route and then characterized by UV–Visible and XRD… Click to show full abstract

Abstract Co0.3Zn0.7Fe2O4 nanoparticles prepared by co-precipitation method were characterized by X-ray diffraction (XRD). Reduced graphene oxide (rGO) was prepared by modified Hummer's route and then characterized by UV–Visible and XRD techniques. Nano-heterostructures of Co0.3Zn0.7Fe2O4 with rGO were prepared using ultra-sonication technique. XRD analysis of Co0.3Zn0.7Fe2O4 nanoparticles and Co0.3Zn0.7Fe2O4-rGO confirmed the cubic structure of ferrite nanoparticles. Cyclic voltammetry experiments showed that Co0.3Zn0.7Fe2O4-rGO nano-heterostructures exhibit the greater value of specific capacitance (151.33 Fg−1) as compared to Co0.30Zn0.70Fe2O4 nanoparticles (91.20 Fg−1). These values of specific capacitance were observed at 10 mV s−1. Moreover, electrochemical impedance spectroscopy showed that Co0.3Zn0.7Fe2O4-rGO nano-heterostructures have lower charge transfer resistance than the bare Co0.3Zn0.7Fe2O4 nanoparticles. Electrochemical experiments illustrated that Co0.3Zn0.7Fe2O4-rGO nano-heterostructures have efficient energy storage properties and can be utilized for electrode's fabrication in supercapacitors.

Keywords: 3zn0 7fe2o4; nano heterostructures; 7fe2o4 rgo; co0 3zn0

Journal Title: Ceramics International
Year Published: 2018

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