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Sintered TiO2 powder containing metallic Co binder prepared via mechanical carbonization, and its mechanical properties

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Abstract A TiO 2 -Co-a composite powder was prepared via carbonizing and selective oxidation processing of a Ti-Co alloy. The conventionally mixed TiO 2 -Co-c composite powder and pure TiO… Click to show full abstract

Abstract A TiO 2 -Co-a composite powder was prepared via carbonizing and selective oxidation processing of a Ti-Co alloy. The conventionally mixed TiO 2 -Co-c composite powder and pure TiO 2 were sintered at 1100, 1200, 1300, 1400 °C, respectively. The structural characterization was performed using X-ray diffraction, field emission scattering electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The sintered samples were more densified, and melted bonding occurred at temperature higher than 1300 °C. The flexural strength and fracture toughness of the TiO 2 -Co-a sample were higher than those of the TiO 2 and TiO 2 -Co-c sintered at temperature higher than 1300 °C, while the Vickers hardness of TiO 2 -Co-a was the lowest at all sintering temperatures. The sintered TiO 2 -Co-a sample was more ductile and strengthened than the TiO 2 -Co-c sample with added metallic Co binder via mechanical mixing. The enhanced mechanical properties of the TiO 2 -Co-a sample were due to the fine dispersion of the metallic Co binder wetted with a TiO 2 matrix.

Keywords: microscopy; tio; powder; prepared via; metallic binder

Journal Title: Ceramics International
Year Published: 2018

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