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Improved Li and Sb doped lead-free (Na,K)NbO3 piezoelectric ceramics for energy harvesting applications

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Abstract Piezoelectric energy harvesting is the most widely investigated technology for renewable energy applications. In this work, (1-x)(Na0.5K0.5)NbO3-xLiSbO3 piezoelectric ceramics were prepared through conventional mixed oxide fabrication methods with different… Click to show full abstract

Abstract Piezoelectric energy harvesting is the most widely investigated technology for renewable energy applications. In this work, (1-x)(Na0.5K0.5)NbO3-xLiSbO3 piezoelectric ceramics were prepared through conventional mixed oxide fabrication methods with different sintering temperatures. Although the (Na0.5K0.5)NbO3 piezoelectric material is representative among the lead-free ceramics, it is difficult to densify by typical sintering techniques owing to its easy evaporation properties of potassium (K+) and sodium ion (Na+). Hence, lithium (Li+) and antimony ion (Sb5+) were used for the partial substitution of (Na0.5K0.5)NbO3. With the optimized sintering temperature, Li+ and Sb5+ are expected to be crucial in increasing the density and enhance the piezoelectric and ferroelectric properties. In this study, the phase, microstructure, and dielectric and electrical properties of (1-x)(Na0.5K0.5)NbO3-xLiSbO3 ceramics depending on the sintering temperature is examined by employing X-ray diffraction, field emission scanning electron microscopy, impedance analyzer, and mechanical force system for energy harvesting.

Keywords: energy; piezoelectric ceramics; na0 5k0; energy harvesting; nbo3 piezoelectric; 5k0 nbo3

Journal Title: Ceramics International
Year Published: 2018

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