LAUSR

Abstract Thanks to the high optical transparency and ultra-low thermal conductivity, silica aerogels are ideal materials for energy-saving windows. However, their preparation is commonly based on either one-step base-catalyzed method, or two-step acid-base catalyzed method, which is difficult to inhibit the aggregation of clusters while keeping the size of clusters as small as possible and thus degrading silica aerogel's properties. Here, a new idea for synthesizing silica aerogels is presented from the viewpoint of controlling the growth and aggregation of silica clusters. A certain amount of Tetramethoxysilane (TMOS) used as seed precursor is firstly added into the mixture of methanol and distilled water for hydrolysis. A certain time later, the additional TMOS and a defined amount of ammonia are added to the obtained sol for promoting the rapid formation of the gel in several minutes. The silica aerogels prepared by this method have higher optical transparency and lower thermal conductivity than those prepared by the other two methods. This approach may also shed substantial light on controlling the microstructure of other materials prepared by sol-gel process.