Abstract Boron carbide submicron powder was synthesized with boron oxide and graphene as starting materials by gas-solid reaction method using two different apparatuses. The effects of calcination temperature and holding… Click to show full abstract
Abstract Boron carbide submicron powder was synthesized with boron oxide and graphene as starting materials by gas-solid reaction method using two different apparatuses. The effects of calcination temperature and holding time, apparatus type and B 2 O 3 /C ratio of the starting materials on the phase composition and morphology of the synthesized powders were evaluated. A newly formed residual carbon morphology distinct from original graphene were present in samples synthesized at a higher B 2 O 3 /C ratio or temperature. The synthesis temperature of ∼1500 °C was found to be more suitable to obtain boron carbide powder without the existence of residual carbon. The new type of apparatus enabled the synthesis of boron carbide phase at a relatively lower temperature, due to its more efficient use of B 2 O 3 vapor.
               
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