LAUSR

Abstract A network-like structure consisting of an amorphous nickel–cobalt layered double hydroxide nanofilm anchored to Co 3 O 4 nanowires (Co 3 O 4 /NiCo-LDH) is grown on nickel foam via hydrothermal reaction and electrochemical deposition. The complex interlocking network-like structure provides three-dimensional interconnected porous channels for electron transport and ion diffusion, and provides optimal access to active sites; this results in rapid Faradaic redox reactions. This intriguing advantage gives the optimal Co 3 O 4 /NiCo-LDH electrode outstanding electrochemical performance, with an ultrahigh specific capacity of 1067 C g -1 , and high rate performance, with 73.28% capacity retention at 20 A g -1 . When it is combined with an activated carbon (AC) electrode, the Co 3 O 4 /NiCo-LDH//AC device exhibits a maximum energy density of 74.4 Wh kg -1 at a power density of 989 W kg -1 and excellent cycling stability, with 91.57% retention after 7000 cycles. This study provides new options and an important foundation for rational design of network-like structures for application in hybrid supercapacitors.