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Spark Plasma Sintering of double perovskite Ba2MgWO6 doped with Ce3+: Part I - Structural and microstructural characterizations

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Abstract Ba2MgWO6 (BMW) translucent ceramics undoped or doped with Ce3+ were prepared by using Spark Plasma Sintering (SPS) method. Powders with submicrometric particles diameter and composed of pure BMW cubic… Click to show full abstract

Abstract Ba2MgWO6 (BMW) translucent ceramics undoped or doped with Ce3+ were prepared by using Spark Plasma Sintering (SPS) method. Powders with submicrometric particles diameter and composed of pure BMW cubic phase were fabricated by simple solid-state reaction from primary powders. This work highlights that thermomechanical schedule applied during sintering must be carefully chosen as BMW tends to decompose for temperatures above 1400 °C. As a result, dense and translucent undoped BMW and BMW:Ce3+ ceramics were obtained at only 1350 °C for 5 min under 50 MPa of uniaxial pressure. Such lanthanide-free ceramics with high density (i.e. 6.8–7.2 g/cm−3) could be envisaged as new and more environmentally-sustainable scintillators for medical imaging.

Keywords: bmw; ba2mgwo6; plasma sintering; spark plasma; doped ce3; sintering double

Journal Title: Ceramics International
Year Published: 2020

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