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Relaxor ferroelectric (Na0.5Bi0.5)0.4Sr0.6TiO3-based ceramics for energy storage application

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Abstract Lead-free (Na0.5Bi0.5)0.4Sr0.6TiO3-xK0.73Bi0.09NbO3 (abbreviated as NBST-xKBN) ceramics with perovskite structure were prepared by a conventional solid-state reaction method. NBST ceramics modified with KBN content demonstrate strong relaxor behavior. When x = 0.05,… Click to show full abstract

Abstract Lead-free (Na0.5Bi0.5)0.4Sr0.6TiO3-xK0.73Bi0.09NbO3 (abbreviated as NBST-xKBN) ceramics with perovskite structure were prepared by a conventional solid-state reaction method. NBST ceramics modified with KBN content demonstrate strong relaxor behavior. When x = 0.05, the optimal energy storage density (1.79J/cm3), improved recoverable energy efficiency (91.02%) and the maximum dielectric breakdown strength (22.2 kV/mm) are obtained. The discharge energy density of NBST-0.05KBN are measured under the electric field from 10 kV/mm to 16 kV/mm, exhibiting good discharge energy density (1.20J/cm3) at 16 kV/mm. Complex impedance plots of NBST-xKBN exhibit great resistivity of the ceramics. In all, these results indicate that NBST-xKBN is a potential candidate for energy storage applications.

Keywords: 5bi0 4sr0; energy; energy storage; 4sr0 6tio3; na0 5bi0

Journal Title: Ceramics International
Year Published: 2020

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