LAUSR

Abstract Relaxor ferroelectric 0.75 Pb(Mg1/3Nb2/3)O3-0.25PbTiO3 (0.75PMN-0.25PT) ceramics with Mn-doping concentration of 0%, 1%, 2% and 3 mol% were prepared by two-step sintering. The phase composition, microstructure, dielectric property, ferroelectric property, piezoelectric property and electromechanical property were investigated. Results indicate that all ceramics exhibit pure perovskite phases and high density. Mn-doping induces some decrease in dielectric constant er, dielectric loss tanδ, remnant polarization Pr, piezoelectric coefficient d33, and electromechanical coupling coefficient kp, while significant increase in mechanical quality factor Qm and the figure of merit (FOM) of 0.75PMN-0.25PT ceramics. For 3 mol% Mn-doped 0.75PMN-0.25PT ceramics, Qm enhances by 1449%, FOM increases by 923%, and tanδ decreases by 67%, which makes it more suitable for high power applications. Interestingly, double P-E loops are observed in 3 mol% Mn-doped 0.75PMN-0.25PT ceramics. The phenomenon was investigated by the symmetry-conforming principle of point defects and the internal bias field.