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Enhanced nitrogen dioxide sensing properties of Ni4Cr1/SnO2 heterostructures

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Abstract Highly sensitive nitrogen dioxide (NO2) gas sensors were prepared based on NiCr/SnO2 heterostructures of conducting films. NiCr/SnO2 heterostructures were developed by DC sputtering of NiCr target followed by RF… Click to show full abstract

Abstract Highly sensitive nitrogen dioxide (NO2) gas sensors were prepared based on NiCr/SnO2 heterostructures of conducting films. NiCr/SnO2 heterostructures were developed by DC sputtering of NiCr target followed by RF sputtering of SnO2. Annealing of heterostructures at 600°C leads to high crystallinity as well as good adhesion to the substrate. The sensor platform is based on planar interdigitated electrodes. The surface morphology and structural properties of NiCr/SnO2 heterostructures were examined by field emission scanning electron microscopy (FESEM), Energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The NO2 gas sensing properties were studied at different operation temperatures (25–250 °C) and gas concentrations (5–100 ppm). The results exhibit a sensing response of 6.9 for 100 ppm NO2 with fast recovery times ~ 5s, and 7s, respectively. The synergetic effects induced by the NiCr-decoration including enhanced response and lowered operation temperature were observed. The sensing mechanism of the NiCr/SnO2 heterostructures sensor was also discussed in detail. It is reported that as-prepared sensors based on NiCr/SnO2 heterostructures display a phenomenal option for utilizing in the field of a gas sensor for attaining very high 3-S parameters (sensor response, selectivity, and stability).

Keywords: nitrogen dioxide; sno2 heterostructures; spectroscopy; sensing properties; nicr sno2

Journal Title: Ceramics International
Year Published: 2020

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