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Insight into a Eu2+-activated zirconium-silicate yellow phosphor for multifunctional applications

Abstract To better meet the needs of modern science and technology for new inorganic functional materials, the exploration of new Eu2+-doped phosphors is of great significance. In this work, a… Click to show full abstract

Abstract To better meet the needs of modern science and technology for new inorganic functional materials, the exploration of new Eu2+-doped phosphors is of great significance. In this work, a zirconium-silicate yellow phosphor, K2ZrSiO5:Eu2+, was explored through theoretical calculations and systematic experiments for use in multifunctional applications. The crystal structure, electronic structure, photoluminescence (PL) and cathodoluminescence (CL) properties of K2ZrSiO5:Eu2+ were investigated in detail. As a result, owing to the open framework and the lattice with the covalent connection, K2ZrSiO5:Eu2+ phosphor exhibits strong yellow light emission under the near-ultraviolet and electron beam excitation. However, the K2ZrSiO5:Eu2+ phosphor suffers a poor thermal stability. Furthermore, the K2ZrSiO5:Eu2+ phosphor exhibits good anti-saturation and anti-aging characteristics under the electron beam excitation. The results indicate that the development of K2ZrSiO5:Eu2+ phosphor can provide a new insight into discovering multifunctional materials.

Keywords: k2zrsio5 eu2; yellow phosphor; zirconium silicate; phosphor; silicate yellow

Journal Title: Ceramics International
Year Published: 2020

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