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Ultrahigh and field-independent energy storage efficiency of (1-x)(Ba0.85Ca0.15)(Zr0.1Ti0.9)O3-xBi(Mg0.5Ti0.5)O3 ceramics

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Abstract Relaxor ferroelectrics are attracting an increasing interest in the application of pulse power systems due to their excellent energy storage performance. In this paper, the (1-x)(Ba0·85Ca0.15)(Zr0·1Ti0.9)O3-xBi(Mg0·5Ti0.5)O3 ((1-x)BCZT-xBMT, x ≤ 0.2) relaxor… Click to show full abstract

Abstract Relaxor ferroelectrics are attracting an increasing interest in the application of pulse power systems due to their excellent energy storage performance. In this paper, the (1-x)(Ba0·85Ca0.15)(Zr0·1Ti0.9)O3-xBi(Mg0·5Ti0.5)O3 ((1-x)BCZT-xBMT, x ≤ 0.2) relaxor ceramics are prepared by the solid state method. The influence of BMT on the microstructure, dielectric and energy storage properties of the prepared ceramics is investigated. The XRD results show that the peak intensity of impurities (Bi2O3, TiO2 and Ba2Bi4Ti5O18) is gradually stronger than that of BCZT phase with x increasing. Meanwhile, the grain size of (1-x)BCZT-xBMT ceramics gradually increases on account of the appearance of impurities Bi2O3. Influenced by the impurities and BMT, the dielectric constant of prepared ceramics gradually decreases with x increasing. A large Wrec value of 0.65 J/cm3 with an ultrahigh η value of 97.89% is achieved at x = 0.15 due to the high breakdown strength and slim P-E hysteresis loop. Meanwhile, the η is insensitive to the electric field. The ultrahigh η leads to lesser energy loss during the charge and discharge process. It makes the 0.85BCZT-0.15BMT ceramic more attractive in the application of pulse power systems.

Keywords: zr0 1ti0; energy; ba0 85ca0; energy storage; 85ca0 zr0

Journal Title: Ceramics International
Year Published: 2020

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