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Luminescence properties and applications of Ce3+-activated Lu3Mg2GaSi2O12 yellow-green emission garnet phosphors

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Abstract Ce3+-doped Lu3Mg2GaSi2O12 (LMGS) yellow-green phosphors were synthesized by a high-temperature solid-state reaction method for 3 h. The optical properties and crystal structure of the obtained samples were characterized by spectral… Click to show full abstract

Abstract Ce3+-doped Lu3Mg2GaSi2O12 (LMGS) yellow-green phosphors were synthesized by a high-temperature solid-state reaction method for 3 h. The optical properties and crystal structure of the obtained samples were characterized by spectral analysis and Rietveld refinement, respectively. The emission spectra excited by 460 nm exhibit broad yellow-green emission bands from 525 to 535 nm (having short redshift with increasing Ce3+ concentration). At 423 K, the emission intensity of the LMGS: 0.0015Ce3+ phosphor decreases to 81.94% of that at room temperature, and the activation energy is approximately 0.153 eV. The samples presented good water resistance. Finally, we packaged the obtained green phosphors and commercial red phosphors Sr2Si5N8: Eu2+ with a blue LED chip. The color-rendering index and correlated color temperature of the packaged w-LED under 460 nm excitation were 84.2 and 4034, respectively. All the above results indicate that the LMGS: Ce3+ samples have great potential for applications in w-LEDs.

Keywords: luminescence properties; properties applications; emission; applications ce3; green emission; yellow green

Journal Title: Ceramics International
Year Published: 2021

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