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Comparison of visible and IR transparency of MgO and in situ synthesized LiF decorated on MgO nanoparticles consolidated by spark plasma sintering

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Abstract In this study, infrared (IR) and visible transparent MgO ceramics were obtained by spark plasma sintering of in-situ synthesized of LiF decorated MgO nanoparticles (MgO–LiF nanocomposite). Lithium acetate (LiAC),… Click to show full abstract

Abstract In this study, infrared (IR) and visible transparent MgO ceramics were obtained by spark plasma sintering of in-situ synthesized of LiF decorated MgO nanoparticles (MgO–LiF nanocomposite). Lithium acetate (LiAC), trifluoroacetic acid (TFA), oleic acid (OA), and absolute ethanol were used as in-situ synthesis of the LiF phase covered on MgO nanoparticles. TFA/Li (AC) mole ratio, pH, and calcination temperature were changed to obtain the MgO–LiF nanocomposite. The results revealed that with Li (AC)/TFA = 1.5:0.5 and pH = 6 at the calcination temperature of 700 °C, in situ MgO–LiF nanocomposites were well prepared. The SPSed MgO covered with a 0.5% LiF sample showed 30% more visible and IR transmittance than pure MgO bodies sintered at 1100 °C for 10 min.

Keywords: mgo nanoparticles; situ synthesized; mgo; plasma sintering; spark plasma; synthesized lif

Journal Title: Ceramics International
Year Published: 2021

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