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Low-temperature sintering and electrical properties of Ba0.68Sr0.32TiO3 thick films

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Abstract Ba0.68Sr0.32TiO3(BST) thick films were prepared by screen printing on a flexible fluorophlogopite substrate. In order to realise the co-firing of the BST film with a silver electrode at a… Click to show full abstract

Abstract Ba0.68Sr0.32TiO3(BST) thick films were prepared by screen printing on a flexible fluorophlogopite substrate. In order to realise the co-firing of the BST film with a silver electrode at a lower temperature, the BST precursor was used as a solvent for the screen-printing slurry and the cold sintering technique was used to pretreat the film. The sintering temperature of BST thick films prepared by conventional sintering process was higher than 1200 °C. When sintered at 950 °C, the thick films exhibited a high porosity. The density of the thick films was significantly improved after pretreatment with the cold sintering process(CSP). After the cold-sintered thick films were sintered at 950 °C for 30 min and then fired with a silver electrode, the samples exhibited a relative dielectric constant of 773 (at 25 °C and 10 kHz), a dielectric loss of 0.025, a remanent polarisation of 5.3 μC/cm2, and a coercive field strength of 38.1 kV/cm. Therefore, the low-temperature co-firing of BST thick films with a silver electrode was successfully realised.

Keywords: 68sr0 32tio3; ba0 68sr0; thick films; temperature; low temperature; bst

Journal Title: Ceramics International
Year Published: 2021

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