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Cofiring of LTCC multilayer assemblies with integrated NTC thermistor temperature sensor layers

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Abstract We have studied the integration of Ni–Co–Zn–Mn spinel NTC thermistor layers into LTCC multilayer modules. Sintering of the cubic spinel Ni0.5Co0.5Zn0.75Mn1.25O4 with addition of 3 wt% Bi2O3 additive at 900 °C… Click to show full abstract

Abstract We have studied the integration of Ni–Co–Zn–Mn spinel NTC thermistor layers into LTCC multilayer modules. Sintering of the cubic spinel Ni0.5Co0.5Zn0.75Mn1.25O4 with addition of 3 wt% Bi2O3 additive at 900 °C resulted in samples with 96% density and with good electrical performance. Thermistor spinel tapes, fabricated using doctor blade tape casting, were stacked with layers of a commercially available low-k dielectric LTCC tape, and cofired at 900 °C. Free or constrained cofiring did not give crack-free multilayer samples. Thermistor layers were then integrated combining the commercial LTCC tape with a Zn titanate-based tape in one multilayer laminate, and error-free multilayer samples with a room-temperature resistivity of ρ298 = (2,9 ± 0.08) kΩcm and a thermistor constant of B = (4280 ± 200) K were obtained. This demonstrates the possibility of cofiring of functional ceramic and low-k LTCC tapes and shows the potential of NTC spinel thermistor layers as temperature sensors integrated in complex LTCC multilayer architectures.

Keywords: tape; ntc thermistor; thermistor; ltcc multilayer; multilayer

Journal Title: Ceramics International
Year Published: 2021

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