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Synthesis and characterization of sponge-like α-Fe microtubes

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Abstract Sponge-like magnetic α-Fe microtubes have been prepared via reduction of α-Fe 2 O 3 microtubes in hydrogen flow. α-Fe 2 O 3 microtubes have been previously obtained by combined… Click to show full abstract

Abstract Sponge-like magnetic α-Fe microtubes have been prepared via reduction of α-Fe 2 O 3 microtubes in hydrogen flow. α-Fe 2 O 3 microtubes have been previously obtained by combined sol-gel and template methods. It is shown that the strongly acidic aqueous medium leads to specific interaction of ferric hydroxide nanoparticles with cellulose template. This contributes to the formation of α-Fe 2 O 3 microtubes, which retain the features of the initial fibers structure. Both calcination at high temperature (1200 °C) and reduction does not lead to the destruction of the tubular morphology. The resulting magnetic materials have a promising applications in biomedicine, as micro-reactors, microwave absorbing materials, easily recoverable from the reaction medium catalysts of various chemical reactions (including carbon nanotubes growth) and a component for creating new composite (e.g., metal-oxide) materials with improved performance characteristics.

Keywords: sponge; like microtubes; characterization sponge; sponge like; synthesis characterization

Journal Title: Chemical Engineering Science
Year Published: 2017

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