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Colloidal detachment from solid surfaces: Phase diagrams to determine the detachment regime

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Abstract Particle detachment during colloidal-suspension transport in porous media occurs in chemical and environmental engineering. Breach of the attached particles mechanical equilibrium conditions yields their mobilisation by rolling, sliding, or… Click to show full abstract

Abstract Particle detachment during colloidal-suspension transport in porous media occurs in chemical and environmental engineering. Breach of the attached particles mechanical equilibrium conditions yields their mobilisation by rolling, sliding, or lifting. We introduced a novel phase diagram indicating the detachment regime for given transport conditions. The phase diagram structure follows from the mechanical equilibrium conditions. Seven series of laboratory tests in visualisation cell with various parameters have been conducted. Placing the observed detachment parameters on phase diagrams shows that rolling is the dominant detachment regime. A gradual detachment of particles was explained by a probabilistic distribution of the particle and surface parameters, and a novel method for the probabilistic distribution determination is developed. For the laboratory tests performed, correlating the critical velocity for particle mobilisation with asperity size allowed obtaining the asperity distribution on the substrate. The obtained distributions were in agreement with reported values of surface roughness on glass coverslips.

Keywords: detachment regime; phase diagrams; detachment; colloidal detachment

Journal Title: Chemical Engineering Science
Year Published: 2021

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