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High precision U-series dating of scleractinian cold-water corals using an automated chromatographic U and Th extraction

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Abstract High-precision U-series dating of scleractinian cold-water corals is a key chronological tool for studies of past environmental and climate conditions. Here, we tested and optimized an automated chemical extraction… Click to show full abstract

Abstract High-precision U-series dating of scleractinian cold-water corals is a key chronological tool for studies of past environmental and climate conditions. Here, we tested and optimized an automated chemical extraction system (ESI prepFAST-MC equipped with an Eichrom TRU-resin chromatographic column) for its ability to purify U and Th isotopes for mass spectrometric U-series dating at the sub-‰ precision level. Chemical yields are constantly high, on average around 90% for both U and Th. Analytical blanks are comparable to manual purification (  1 μg g− 1 Th and U in order to achieve the above mentioned chemical yields. This conditioning has no impact on the Th/U data. The automated chemical preparation protocol described here is compared to conventional high precision U-series dating with manual sample purification. For the 34 cold-water corals extracted from a sediment core collected from a coral mound off Angola, the differences between 230Th/238U- and 234U/238U-ratios and U-series ages measured with the two analytical methods are smaller than the respective analytical uncertainty of

Keywords: cold water; high precision; series dating; series; precision series

Journal Title: Chemical Geology
Year Published: 2017

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