LAUSR

With the development of dye production and printing industry, dyes wastewater has increased dramatically. The resulting environmental pollution problem is increasing seriously. In the present work, a porphyrin-based porous organic polymer (PPOPs-OH) was synthesized by using pyrrole and 2,6-dihydroxynaphthalene-1,5-dicarbaldehyde (DHNDA) as basic building block in situ. This method was cost- and time-efficient, without the participation of metal catalysts. Further reaction of PPOPs-OH with chlorosulfonic acid, a new sulfonic acid functional material (PPOPs-SO3H) was obtained with the increasing electronegativity and hydrophilicity. PPOPs-SO3H exhibit good adsorption capacity for methylene blue (MB) from water (980.4 mg g-1) and excellent selectivity for MB in the present of rhodamine B (RhB) and methyl orange (MO). Mechanism investigation revealed that electrostatic in comparison with π-π interaction is the prominent force in the absorption process. Recycling experiments found the absorption properties of PPOPs-SO3H did not reduce significantly after several cycles. As a consequence, our findings highlight an appealing opportunities for covalent organic polymers with their potential application as high-efficiency and robust adsorbents for pollutants removal and environmental protection.