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Removing the Mask in Catalytic Asymmetric Diamination of Alkenes

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In this issue of Chem , Liu and co-workers report an extremely general and mild radical diamination protocol that permits the asymmetric synthesis of vicinal diamines in a highly enantioselective… Click to show full abstract

In this issue of Chem , Liu and co-workers report an extremely general and mild radical diamination protocol that permits the asymmetric synthesis of vicinal diamines in a highly enantioselective manner under a copper(I)/chiral phosphate dual-catalytic system. Notably, this work represents the first asymmetric radical alkene diamination that allows for direct alkylamine incorporation.

Keywords: diamination; removing mask; asymmetric diamination; mask catalytic; diamination alkenes; catalytic asymmetric

Journal Title: Chem
Year Published: 2017

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