In this issue of Chem, Nagib and co-workers report an operationally simple approach for direct C–H halogenation of arenes and (hetero)arenes through in situ activation of commercially available PhI(OAc)2. The resulting… Click to show full abstract
In this issue of Chem, Nagib and co-workers report an operationally simple approach for direct C–H halogenation of arenes and (hetero)arenes through in situ activation of commercially available PhI(OAc)2. The resulting non-symmetrical iodanes offer chemists new tools for the mild halogenation of arene scaffolds with exquisite selectivity and tunability.
               
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