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More Than Just Acetates: PhI(OAc)2 Enables C–H Halogenation of Arenes

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In this issue of Chem, Nagib and co-workers report an operationally simple approach for direct C–H halogenation of arenes and (hetero)arenes through in situ activation of commercially available PhI(OAc)2. The resulting… Click to show full abstract

In this issue of Chem, Nagib and co-workers report an operationally simple approach for direct C–H halogenation of arenes and (hetero)arenes through in situ activation of commercially available PhI(OAc)2. The resulting non-symmetrical iodanes offer chemists new tools for the mild halogenation of arene scaffolds with exquisite selectivity and tunability.

Keywords: halogenation; enables halogenation; oac enables; acetates phi; halogenation arenes; phi oac

Journal Title: Chem
Year Published: 2019

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